Welded austenitic nickel chromium steels

ABSTRACT

Weld deposits joining nickel-chrome austenitic steels, a method of making the weld deposits and filler metals yielding such weld deposits which have the general composition in per cent by weight of carbon 0.06 to 0.12, chromium 15 to 20, nickel 7.5 to 13, tungsten 3.5 to 5, manganese 0.5 to 2, silicon &lt; OR = 0.6 and nitrogen (N2) &lt; OR = 0.10, and a ferritic tendency index of less than or equal to 15.

United States Patent [191 De Cadenet I WELDED AUSTENITIC NICKEL CHROMIUM STEELS [75] Inventor: Jean-Jacques De Cadenet, Ugin France [73] Assignee: Ugine Aciers, Paris, France 22 Filed: June 9, 1912 [21] Appl. No.: 261,390

Related U.S. Apblication Data [60] Division of Ser. No. 13,757, Feb. 24, 1970, Pat. No. 3,693,247, which is'a continuation-in-part of Ser. No. 608,971, Jan. 13, 1967, abandoned.

[52] US. Cl. 29/l96.1 [51] Int. Cl B32b 15/00 [58] Field of Search 29/1961; 75/128 G [56] References Cited UNITED STATES PATENTS 2,083,524 6/1937 Payson. 75/128 W [4 1 Jan. 15, 1974 2,249,723 7/1941 Orr 29/l96.l

2,802,756 8/1957 Bloom 29/196.1 2,914,346 11/1959 Ryder; 29/1961 3,177,577 4/1965 Fujimura 75/128 W 3,640,690 2/1972 Ries 29/1961 3,620,809 11/1971 Flicker 29/l96.1

Primary Examiner-Hyland Bizot Att0meyJohn M. Webb et a1.

[5 7 ABSTRACT 5 Claims, N0 Drawings WELDED AUSTENITIC NICKEL CHRQMIUM STEELS This is a division of application Ser. No. 13,757 filed Feb. 24, 1970, US. Pat. No. 3,693,247, which is a continuation in part of application Ser. No. 608,971, filed Jan. 13, 1967 now abandoned.

The present invention relates to weld deposits and methods of making weld deposits. More particularly, it relates to fillers and weld deposits adapted for joining austenitic steels resistant to high temperatures and specifically nickel-chrome austenitic steels and steels derived therefrom by the addition of alloying elements.

When steels resistant to high temperature are joined by welding, the applicable requirements are that the welded deposits should be unaffected by fissuration during welding, they should'not become embrittled during an extended period of high temperature application, and they should have creep characteristics comparable to those of the base metal.

Weld deposits of the present invention meet these requirements and provide a weld joint having superior properties to those utilizing weld deposits containing molybdenum which are currently used for welding austenitic steels for high temperature applications.

The weld deposits and filler metals encompassed within the scope of the present invention are substantially nickel-chrome austenitic steels having the following general compositiom Percent Carbon 06 to 0 12 Chromium 15 to 20 Nickel 7.5 to 13 Tungsten 3.5 to Manganese 0.5 to 2 Silicon 0.6 Nitrogen i 0.10

The balance is iron and the normal impurities in steel. The index of ferritic tendency represented by the formula, 3(Cr 0.5 W -1.5 Si 0.93 Ni 28 C 0.46 Mn 15 N 6.7), in which the symbols of the elements represent the proportions expressed in per cent by weight, is equal to or less than 15.

The preferred composition for weld deposits and filler metals within the scope of. this invention is within the following more restricted limits:

Percent Carbon 0.06 to 0.10 Chromium 15 to 17.5 Nickel 7.5 to 9 Tungsten 3.5 to 4.5 Manganese 0.5 to 2 Silicon 0.6 Nitrogen s 0.10

having the composition set forth above. It includes coated electrodes or the tubular filler metals in which the metal core has the composition of the invention and coated electrodes or the tubular filler metals in which the metalcore has a different composition from that of the invention, but in which the coating or filling has a composition such that the metal deposited by welding has the composition of the invention. It also includes any combination between a metal electrode of optional composition and a protective flux or electroconductive slag in which the compositions are such that the metal deposited by welding utilizing the combination has the composition set forth above. And, in general, it includes any combination of compact or pulverulent substances which may be used as an initial welding product that will allow one to obtain a deposited metal having the compositions set forth above. For ease of presentation, this general class of materials described hereinabove will be referred to as filler metal bodies.

Tests have been made comparing the mechanical strength of welded joints made utilizing weld deposits currently used for welding austenitic steels for high temperature and joints made utilizing weld deposits and filler metal bodies within the scope of this invention. I

The method of welding the pieces of austenitic nickel-chrome steels comprises welding the pieces in the presence of a filler metal body to form the weld deposit. The weld deposit has a composition of 0.06 to 0.12 per cent carbon, 15 to 20 per cent chromium, 7.5 to 13 per cent nickel, 3.5 to 5.0 per cent tungsten, 0.5 to 2.0 per cent manganese, up to 0.6 per cent silicon, up to 0.10 per cent nitrogen andthe balance iron and incidental impurities. In Table 1 below, the results of rupture through creepage tests are tabulated. Weld deposit A was a typical molybdenum type deposit con.- taining 0.08 per cent carbon, 16 per cent chrome, 8 per cent nickel, 2.0 per cent molybdenum and the balance iron and incidental impurities. Weld deposit B had a composition within the preferred range of this invention;

The improvement achieved by the weld deposits of this invention (B) compared with prior art deposit (A) is on the order of 5 per cent at 650C. At 700C at the end of hours the improvement in breaking strain has increased to 9 per cent, after 1,000 hours to 18 per cent, and at the end of 10,000 hours to more than 20 per cent.

The test also showed that at 700C, under a given stress for a period of time exceeding 100 hours, breakage as the result of creepage occurs at the end of a period of time that is three times longer in the case of the weld deposits of the present invention than in the case of weld deposits of the prior art.

The substantially austenitic welds containing chromium and nickel, with additions, such as molybdenum and columbium, may become embrittled in service by the formation of intermetallic compounds of the sigma phase type in their structure. This formation may be spread over several thousand hours and may considerably reduce the ductility and resiliency of the welds.

On the other hand, weld deposits of this invention in which the composition lies within the preferred limits specified, and in which the ferritic propensity lies between and 8, have very little tendency to form the sigma phase. The ageing of these new welded deposits at high temperature is principally caused by the formation ofcomplex carbides containing chromium and tungsten, in particular. This results in a much less substantial drop in ductility than the resulting from the formation of the sigma phase. Moreover, this drop in ductility is rapidly followed by. a partial restoration of the properties of the metal. This has been established by the results of tests made on metal deposited by welding, having the composition of 15.6 per cent chromium, 8 per cent nickel, 3.5 per cent tungsten, 0.06 per cent carbon, 1.6 per cent manganese, 0.15 per cent silicon, 0.05 per cent nitrogen, and the balance iron and incidental impurities. The results are set forth in Table II which gives the UP resiliency of the metal.

TABLE 11 UF Resiliency (kgm/cm') The weld deposits of this invention also have a greatly improved resistance to oxidation in air up to 800C. Two specimens were maintained in air at 800C for 200 hours. Both specimens contained 0.09 per cent carbon, 18 per cent chromium, 13 per cent nickel, 1.5 per cent manganese, 0.50 per cent silicon, and 0.06 per cent nitrogen. The balance was iron and incidental impurities (including 0.5 per cent titanium) except that the first specimen contained 2 per cent molybdenum and the second specimen had 3.5 per cent tungsten. The increase in weight per unit surface area of the specimen indicated that the degree of oxidation was 1.5 times greater for the specimen containing molybdenum than for the specimen having a composition within the scope of this invention.

These welded deposits, according to the invention, are particularly appropriate for welding plants such as furnaces or power generation plants operating at high temperature.

From the foregoing it is apparent that this invention provides a novel weld deposit and a method of making it particularly adapted for joining nickel-chrome austenitic steels resistant to high temperatures which results in joints having improved mechanical strength, better ductility and more resistance to oxidation than weld deposits used heretofore.

While the preferred embodiments of this invention have been described, it may be otherwise embodied within the scope of the appended claims.

I claim:

1. A weld deposit joining austenitic nickel-chrome steels consisting essentially of 0.06 to 0.12 per cent carbon, 15 to 20 per cent chromium, 7.5 to 13 per cent nickel, 3.5 to 5.0 per cent tungsten, 0.5 to 2.0 per cent manganese, up to 0.6 per cent silicon, up to 0.10 per cent nitrogen, and the balance iron and incidental impurities.

2. A weld deposit as defined in claim 1 having an index of ferritic tendency no greater than 15.

3. A weld deposit as defined in claim 1 having 0.06 to 0.10 per cent carbon, 15 to 17.5 per cent chromium, 7.5 to 9 per cent nickel, 3.5 to 4.5 per cent tungsten, 0.5 to 2 per cent manganese, up to 0.6 per cent silicon, up to 0.10 per cent nitrogen, and the balance iron and incidental impurities.

4. A weld deposit as defined in claim 3 having an index of ferritic tendency no greater than 8.

5. A welded construction comprising at least two parts and a weld deposit therebetween joining said parts together, said parts being austenitic nickelchrome steels and said weld deposit having a ferritic tendency no greater than 15 and consisting essentially of 0.06 to 0.12 per cent carbon, 15 to 20 per cent chromium, 7.5 to 13 per cent nickel, 3.5 to 5.0 per cent tungsten, 0.5 to 2.0 per cent manganese, up to 0.6 per cent silicon, up to 0.10 per cent nitrogen and the balance iron and incidental impurities.

UNITED STATES PATENT oFFicE CERTIFICATE OF EQMN .Patent No. 3, 785, 786 Dated January 15, 1974 Inventor( Jean- Jacques DeCaclenet It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:

After the line listing the application serial number insert the following:

- -Foreign Application Priority Data January 13,1966 France PV45, 725--.

Signed and sealed this 16th day of April 197M.

(SEAL) Attest:

EDWARD -I=LFLETCHER,JR. C. MARSHALL DANN Attesting Officer v Commissioner of Patents FORM PO-105O (10-69) au.s. GOVERNMENT PRINTING OFFICE: was o-ass-au. 

2. A weld deposit as defined in claim 1 having an index of ferritic tendency no greater than
 15. 3. A weld deposit as defined in claim 1 having 0.06 to 0.10 per cent carbon, 15 to 17.5 per cent chromium, 7.5 to 9 per cent nickel, 3.5 to 4.5 per cent tungsten, 0.5 to 2 per cent manganese, up to 0.6 per cent silicon, up to 0.10 per cent nitrogen, and the balance iron and incidental impurities.
 4. A weld deposit as defined in claim 3 having an index of ferritic tendency no greater than
 8. 5. A welded construction comprising at least two parts and a weld deposit therebetween joining said parts together, said parts being austenitic nickel-chrome steels and said weld deposit having a ferritic tendency no greater than 15 and consisting essentially of 0.06 to 0.12 per cent carbon, 15 to 20 per cent chromium, 7.5 to 13 per cent nickel, 3.5 to 5.0 per cent tungsten, 0.5 to 2.0 per cent manganese, up to 0.6 per cent silicon, up to 0.10 per cent nitrogen and the balance iron and incidental impurities. 